When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | HO2_Nielsen(2002)_298K_240nm.txt |
NAME: | hydroperoxy radical |
FORMULA: | HO2 |
AUTHOR(YEAR): | Nielsen(2002) |
T: | 298K |
λ: | 240nm |
BIBLIOGRAPHY: |
O.J. Nielsen, M.S. Johnson, T.J. Wallington, L.K. Christensen, and J. Platz, "UV absorption cross sections of HO2, CH3O2, C2H5O2 and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3",
Int. J. Chem. Kinet. 34, 283-291 (2002);
DOI: 10.1002/kin.10037
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COMMENTS: | A pulse radiolysis (SF6/H2/O2 mixtures) transient UV-absorption spectroscopy setup has been used
Scaling to σ(CH3O2, 240nm) = (4.24 ± 0.27) ×10-18 cm2 molecule-1, recommended by G.S. Tyndall, R.A. Cox, C. Granier, R. Lesclaux, G.K. Moortgat, M.J. Pilling, A.R. Ravishankara, and T.J. Wallington, "The atmospheric chemistry of small organic peroxy radicals," J. Geophys. Res. D 106, 12157-12182 (2001) |
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